Pedro Muñoz is a municipality in the autonomous community of Castile-La Mancha, Spain. It is located in the northeast corner of the province of Ciudad Real, on the bank of the Záncara river. It is in the La Mancha region, in the "Mancha Alta" sub-region. It is a small municipality, 101.3 km2, due to being abandoned as a municipality in 1410; however, in the late 19th and early 20th centuries it grew into an important economic center in the region.